The Silicon Tetrafluoride – Lab Report – felixdelgado
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The Silicon Tetrafluoride
The silicon tetrafluoride (STF) reacts with 25% caustic solution to form sodium fluoride, sodium silicate and water (see reaction below).
SiF4 + 6NaOH = 4NaF + Na2SiO3 + 3H2O
Assuming 200 pounds of STF are left per tube at a temperature of 298 K and 1 atm.
Table 1. Silicon tetrafluoride
STF left per tube
90702.9
871.48
The current cleaning method uses the following mixture that is refreshed a total of 3 times per trailer.
1000 gallons of water
220 gallons of 25% caustic
AIMM is projecting 2000 gallons of water for their cleaning process (400 gallons per tube).
Table 2. Amount of water per tube
Current
Proposed
600 gal
400 gal
2271.0 L
1514.0 L
2271000 kg
1514000 kg
Table 3. Water Properties
Water Properties @ 25°C
Density
1000 kg/L
Heat Capacity, Cp
4.19 kJ/kg*°C
Table 3. Caustic solution
25% Caustic
M.W. = 40 g/mol
132.00
499.62
1064.19
1064190.60
6651.67
For this analysis the standard enthalpy of reaction was used to calculate the amount of heat produced by this reaction. The enthalpy of reaction is the change that occurs in a system when one mole of matter is transformed by a chemical reaction under standard conditions.
âH_reaction=ââănH_products-ââămHă_reactants ă
Table 4. Enthalpy of formation and molecular weight
Enthalpy of Formation
Molecular Weight
-1615
kJ/mol
104.08
g/mol
-469.15
kJ/mol
40.00
g/mol
kJ/mol
41.99
g/mol
Na2SiO3
-1561.43
kJ/mol
122.06
g/mol
-285.83
kJ/mol
18.01
g/mol
ââănH_(Products )=ă-4694.92 kJ/(mol SiF_4
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By: felixdelgado
Submitted: October 18, 2017
Essay Length: 425 Words / 2 Pages
Paper type: Lab Report Views: 297
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